Sheriff Tiraspol pulled off an enormous shock as they won 2-1 at Real Madrid to make it two wins out of two in Champions League Group D with a late strike from Sebastien Thill.
Jasur Jakhshibaev headed the Moldovan side into the lead in the 25th minute, but Los Blancos were level through a second-half penalty from Karim Benzema, given following a VAR review.
The visitors, though, snatched all three points with just a minute left when Thill drove the ball into the top corner from 20 yards to leave the Bernabeu in stunned silence.
Earlier, newly-crowned heavyweight world champion Oleksandr Usyk was watching in the stands as Shakhtar Donetsk and Inter Milan played out a goalless draw at the Olympic Stadium in Kiev.
Group C: Ajax, Dortmund stay perfect
Ajax maintained their 100 per cent start to Group C with a 2-0 win over Besiktas at the Johan Cruyff ArenA.
Steven Berghuis set Ajax on their way before Sebastien Haller continued his sensational scoring streak with his fifth Champions League goal of the season before half-time.
Elsewhere in Group C, Borussia Dortmund beat Sporting Lisbon 1-0 at Signal Iduna Park thanks to Donyell Malen’s first-half strike, set up by Jude Bellingham.
Lionel Messi scored his first goal for Paris Saint-Germain to help secure a 2-0 win over Manchester City in their Champions League clash at the Parc des Princes.
PSG took an early lead in the seventh minute when City failed to clear a cross into the box and Idrissa Gueye smashed the ball into the top corner.
City responded as Raheem Sterling headed against the crossbar, before Bernardo Silva fired the loose ball back up onto the bar when it looked certain he would score.
Messi, back following a knee problem, capped a fine all-round display when he played a one-two with Kylian Mbappe on the edge of the penalty area and clipped a wonderful finish into the top corner.
PSG move top of Group A, with City down to third after Club Brugge won 2-1 at RB Leipzig.
7 – Lionel Messi has scored more UEFA Champions League goals against Man City (7) than any other player, while his seven goals against sides managed by Pep Guardiola (two vs Bayern Munich, five against Man City with him as manager) are also the most of any player. Haunting. pic.twitter.com/wPAYIZTx2R
— OptaJoe (@OptaJoe) September 28, 2021
Christopher Nkunku put the Bundesliga side ahead in the fifth minute from close range, with the goal given following a lengthy VAR review.
In the 22nd minute, Brugge captain Hans Vanaken saw an equaliser ruled out for offside after the hosts had been caught trying to play out from the back – only for VAR to swiftly overturn the decision.
The Belgians turned things around when they took the lead five minutes before half-time when Mats Rits knocked a loose ball in from six yards.
Liverpool took control of Group B as they ran out 5-1 winners at Porto.
Mohamed Salah put the Premier League side ahead in the 18th minute when he bundled the ball in after Curtis Jones’ angled drive from the left had been pushed out by the ‘keeper.
Sadio Mane tapped home a second just ahead of half-time after James Milner’s cross from the right went right through the six-yard box. Salah added a second just after the hour after being set up by Curtis Jones.
Mehdi Taremi pulled one back for the hosts, only for Roberto Firmino to roll in a fourth on the break after goalkeeper Diogo Costa was caught upfield and could only race back to scoop the ball out from behind the line. The Brazilian added a fifth when tucking in a rebound.
At the San Siro, Luis Suarez netted a stoppage-time penalty as Atletico Madrid came from behind to win 2-1 against AC Milan, who had Franck Kessie sent off in the first half.
The Serie A side were rewarded for a positive start when Rafael Leao drilled in a low shot from the edge of the penalty area in the 20th minute.
Milan, though, were reduced to 10 men just nine minutes later when midfielder Kessie was dismissed for a second caution.
Antoine Griezmann finally levelled things up with six minutes left with a well-taken volley and Suarez had the last word when his scuffed spot-kick squirmed past Mike Maignan.